Apologies to all, let me try to get this topic back on track.
John's requests are good ones so here are the front and gum side of the two stamps under normal light plus a few more samples. I expect John's suggestion that the luminescent portion of the two stamps initially posted where against the plastic portion of a stock page is most likely correct. Certain plastics can have the plasticizer in them migrate into another material they are in contact with. This may responsible for the luminescent effect.
These images take some time to capture good results under LW UV hence the delay in posting. Most images you see taken under LW UV have a very blue tint to them. The images I show are fairly close to what I observe when viewing the stamps under LW. As always images will vary on different monitors but they should be in the ballpark.
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For the two initial samples posted, there is no visible difference when viewed from the front under normal light. Inked image is somewhat visible from gum side.
I also took an image under 40x optical microscope using LW UV of the transition area.
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You can see form of bleed out in the luminescent portion of the samples. I expect this bleed out is a reaction to some form of environmental reaction/impact and contact with stock page.
Below are some additional examples where the entire image is either non-luminescent or luminescent. These may very well be printed with different ink formulations as examples of either type are fairly easy to find. There are many more examples that can be found of other early US stamps
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Below is a slightly different color.
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All images where taken side by side under same LW UV lighting. Visible differences, for example 866, in the background come from different paper many of these were printed on. Different paper brightness can also effect the color ones sees. These views come from a slide presentation I have created to document the many US luminescent and non-luminescent ink varieties.